Most important stuff is already mentioned, but I'll add one important detail:
Consider which are most important accounts (email would be prime candidate) and have the login details for them written up on a physical paper stored in a secure place. This is to prevent catastrophic data loss in the situation where your primary way of managing passwords fails for one reason or the another.
I copy my 1Password keychain onto a USB drive, space is cheap so a 16gig USB drive contains backups going back like 6 months. This drive also includes other bits of data, like tax returns.
There are now two of these drives. Once every two weeks, or after significant changes are made, I rotate them in and out of a safe deposit box.
At home I have the other in a fire safe.
One of my notes in my keychain is also instructions on what to do in case of my inevitable demise :) What credit cards I have, what services I use, all of that type of information.
The master password is stored in a safe location that only immediate family know about. Along with location they know how to handle my affairs if something were to happen to me.
It's a great backup system, but also helps handle taking care of things when I'm gone as 1Password stores data about whatever you want and keeps it secure.
Hope that helps with some more ideas for how to use your password manager to make your life easier.
Consider which are most important accounts (email would be prime candidate) and have the login details for them written up on a physical paper stored in a secure place. This is to prevent catastrophic data loss in the situation where your primary way of managing passwords fails for one reason or the another.